posted April 26, 2000 07:05 PM
Here's an interesting article i picked up from Macmillian Encyclopedia of Chemistry about Super acids:Chemists long considered mineral acids such as sulfuric acid and Nitric acid to be the strongest protic acids. More recently this view has changed considerably with the dicovery of extremely strong acid systems that are hundreds of millions, even billions, of times stronger than 100% concentrated Sulfuric acid. Such acid systems are termed super acids. Hammett's acidity constant measurements (-Hº, a logarithmic scale) HClO4 (-Hº, 13.8); Fluorosulfuric acid (-Hº, 15.1); anhydrous hydrofluoric acid (-Hº, 15.1); Teflic acid (TeF5OH) (-Hº, 15.1); trifluoromethane sulfonic acid (CF3SO3H); and higher homologous perfluoroalkanesulfonic acids (C#F2#+,SO3H) -Hº, 12-14. Well known lewis superacids are Aluminum trihalides (Of Cl, Br, I), Boron trifluoride, AsF5, SbF5, TaF5 and NbF3, Boron tristrifluoromethane sulfonate, B(OSO3CF)3, and gold, tantalum, platinum, niobium fluorosulfonates.
Polysulfuric acids (oleums) sulfuric acid with a 50 mol% SO3, a value of -Hº, 14.5 is reached. "Magic acid": A Fluorosulfuric acid-Antimony pentachloride combination, with 90% SbF5 content in the system, the -Hº reaches 26.5.
Notes: this isn't the whole article on super acids in the mentioned book, it's i guess, what i thought was the most interesting at the time. And the -Hº thing is actually a º where the º, is to the bottom, not the top, the º is the closest that i could find on the character map to match this character.
Super acids attack glass (usually) and metals , as does hydofluoric acid, but without moisture hydrofluoric acid barely even attacks metals or glass, HF regularily doesn't attack high density plastics like HDPE, it could be little different for the super acids. My thought of such a device was that, where the acid is in a resistant shell casing, and the explosive charge would be placed in the middle hole or slot, where when it detonates, the casing is broken by the explosion, exposing the acid to its surrounding atmosphere, "eating" the glass or attacking the metal or armor. Another thing is that the Super acids such as Fluorosulfuric acid (HSO3F) are HIGHLY toxic.
I just had to correct that HClO was HClO4, and it was a typing error. As was SbF3, is SbF5.
[This message has been edited by überchlor (edited April 29, 2000).]